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  Progress in Chemistry, 2007, Vol. 19, Issue (9) : 1282-1290 Current Issue | Next Issue | Archive  
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  Fang Xiaoming**, Zhang Zhengguo, Chen Qinglin . Nitrogen Doped TiO2 Photocatalysts with Visible-Light Activity  Progress in Chemistry, 2007, 19(9): 1282-1290 {, DOI: }
  方晓明,张正国,陈清林. 具可见光活性的氮掺杂二氧化钛光催化剂*  化学进展, 2007, 19(9): 1282-1290 {, DOI: }
Review
Nitrogen Doped TiO2 Photocatalysts with Visible-Light Activity
Fang Xiaoming**; Zhang Zhengguo; Chen Qinglin
The Key lab of Enhanced Heat Transfer and Energy Conservation, Ministry of Education, School of Chemical and Energy, South China University of Technology, Guangzhou 510640, China
Abstract: Anion-doped TiO2 photocatalysts are considered the second-generation photocatalytic materials, which nitrogen doped TiO2 is the representative. The methods for preparing nitrogen doped TiO2 were systematically reviewed, and some controversy concerning the origin of visible-light responses for N-doped TiO2 and the state of N doped in TiO2 matrix were expanded in this paper. The methods for preparing nitrogen doped TiO2 powders mainly include the heat treatment under NH3 flow, the hydrolytic precipitation, the sol-gel process and the mechanochemical method. The methods for preparing nitrogen doped TiO2 films mainly include magnetron sputtering, pulsed laser deposition and metal-organic chemical vapor deposition. several different mechanisms for the visible-light activity of N-doped TiO2 have been proposed, which are the mixing of N 2p and O 2p orbits, the formation of an N-induced isolated narrow band, the presence of oxygen vacancies, and the sensitization by paramagnetic impurity. The controversy concerning the state of N doped in TiO2 matrix lies in the assignment of the peak feature in the XPS N 1s spectrum foTiO2r nitrogen doped TiO2. Finally, the problems involved studies on nitrogen doped TiO2 photocatalysts and the future developing trends are presented.
Key words: photocatalysis   TiO2   visible-light activities   nitrogen doping  
Received: 2006-09-14  Revised: 2006-12-05 
Corresponding Authors: Fang Xiaoming
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Articles by Fang Xiaoming; Zhang Zhengguo; Chen Qinglin
Articles by Fang Xiaoming; Zhang Zhengguo; Chen Qinglin
Articles by Fang Xiaoming; Zhang Zhengguo; Chen Qinglin
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